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Metallocene Anions

Metallocene Anions: Electrochemical Curiosities and Isolable Complexes

October 2, 2023 |

Metallocene Anions: From Electrochemical Curiosities to Isolable Complexes. The vast majority of 3d metallocenes contain metal centres in formal +II or +III oxidation states. Here we review progress in metallocene anion chemistry, with the metal centre in a formal +I oxidation state, focusing on low temperature electrochemical studies and synthetically isolated d-block examples.

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Download Chemistry Development Kit

Download Chemistry Development Kit 2.5

September 9, 2023 |

Chemistry Development Kit (CDK) toolkit software free download is computer software, a library in the programming language Java, for chemoinformatics and bioinformatics. CDK is currently used in several applications, including the programming language R, CDK-Taverna (a Taverna workbench plugin), Bioclipse, PaDEL, and Cinfony. Also CDK extensions exist for Konstanz Information Miner (KNIME) and for Excel, called LICSS.

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Phenylsilsesquioxane Complexes with 8-Hydroxyquinoline Ligands

Phenylsilsesquioxane Complexes with 8-Hydroxyquinoline Ligands

August 18, 2023 |

A Novel Family of Cage-like (CuLi, CuNa, CuK)-phenylsilsesquioxane Complexes with 8-Hydroxyquinoline Ligands: Synthesis, Structure, and Catalytic Activity. Nanosized silsesquioxane [RSiO1.5]n units bridge a gap between organics and inorganics with their pure inorganic Si-O-Si main chain, surrounded by various organic substituents. Silsesquioxanes are often regarded as unique molecular models of silica, both for investigations into surface phenomena and heterogeneous catalysis.

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High-entropy alloy nanoparticles synthesis

High-entropy alloy nanoparticles synthesis

June 24, 2023 |

Liquid metal for high-entropy alloy nanoparticles synthesis (HEA-NPs) shows great potential as functional materials. However, thus far, the realized high-entropy alloys have been restricted to palettes of similar elements, which greatly hinders the material design, property optimization and mechanistic exploration for different applications.

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