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Protonating Tricarboxybenzenes

Protonating Tricarboxybenzenes

May 1, 2022 |

Tricarboxybenzenes were (tri-)protonated, resulting in the formation of astonishingly stable species. The different isomers are stabilized by mesomerism and hyperconjugation depending on the substitution pattern. These effects are observable by X-ray diffraction and NMR spectroscopy and also computable by NPA and NICS calculations, enabling qualitative and quantitative statements.

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Tunable metal hydroxide–organic frameworks

Tunable metal hydroxide–organic frameworks

April 19, 2022 |

Tunable metal hydroxide–organic frameworks for catalysing oxygen evolution. Now MIT researchers have developed a completely new type of catalyst material called the Metal-Organic Hydroxide Framework (MHOF), which is made up of inexpensive and abundant components. and The oxygen evolution reaction is central to making chemicals and energy carriers using electrons.

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